aaronq
  • aaronq
does anyone where i can find isolobal fragment substitution exercises?
Chemistry
schrodinger
  • schrodinger
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abb0t
  • abb0t
What's isobal fragment substitution?
aaronq
  • aaronq
isolobal analogies i can explain or i can show you a link since i can't really draw pictures well on this http://www.adichemistry.com/inorganic/cochem/isolobality/isolobal-analogy.html
abb0t
  • abb0t
Oh! I think i'm more familiar with the term "isoelectronic" idk if it's the same.

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aaronq
  • aaronq
isoelectronic is more about the number of electrons, this is more about the molecular orbitals
aaronq
  • aaronq
abb0t
  • abb0t
I don't know about isobal, but I do know that a d7 complex has one electron in it's eg set allowing for pi-backbonding
aaronq
  • aaronq
would you deduce that from the location of the orbital given that it's octahedral?
abb0t
  • abb0t
Yes. Assuming octahedral geometry, you have 3 orbitals in the t2g set, dxy, dxz, and dyz. and x2-y2 and z2 in the eg set (antibonding) which are higher in energy.
abb0t
  • abb0t
assuming d7, you would have the t2g set filled and one electron in the eg set allowing bonding.
abb0t
  • abb0t
allowing to bond with a molecule that donates one electron? Such as methane.
abb0t
  • abb0t
I don't know abt isobal, but i'm just going by what I think might be relevant? So I am not sure if i am actually answering your question correctly. Lol sorry abt that.
aaronq
  • aaronq
thanks man, any input is helpful for a well-rounded understanding of chem, specially inorganic chem, which you're one of the few people on this site that actually know about. lol btw, which textbook did you use?
abb0t
  • abb0t
Inorganic Chemistry by Meissler 3rd ed. But i hear 4th ed is by far best
aaronq
  • aaronq
did you find it hard to read? I'm using Housecroft for my class but it honestly takes me forever to read a few pages, it's way too dense.
abb0t
  • abb0t
I have the PDF version, if u have dropbox, u can download it. it was pretty clear.
aaronq
  • aaronq
hmm how large is the file?
abb0t
  • abb0t
27.1 MB
aaronq
  • aaronq
i don't have any file sharing accounts. could you email it to me in like 2 parts? lol
abb0t
  • abb0t
hmm...well its useful. i just prefer my USB. lol. but i'll send u the link. give me 2 mins.
aaronq
  • aaronq
haha yeah ubs' are way more useful. thanks
abb0t
  • abb0t
I'll msg u the log in info so u can log in and download it.
aaronq
  • aaronq
aight, thanks, i appreciate it.
abb0t
  • abb0t
should work. if not lemme know.
aaronq
  • aaronq
dope, it worked. thanks alot

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