What does Chargaff's rule state? And what did Watson and Crick do?

What does Chargaff's rule state? And what did Watson and Crick do?

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if you have 40% G-C, that means you have 20% G and 20% C.
hence, you have 60% A-T pairs.

So it doesn't mean that it has to be 50-50, right?

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